DrivePool has a feature called Read Striping, which you can turn on. If the folder is duplicated, DrivePool will read from both drives and that can speed up the read task. If you expand the performance tab, you can see both drives that DrivePool is reading from and the speed at which it is reading. You can almost double the read speed in some transfers.
What I see on my system is that DrivePool will read from both my SSD and an archive HDD at the same time, but since the SSD is just so much faster, most of the read data comes from the SSD. I don't know if DrivePool is specifically programmed to recognize the faster drive and use that pipeline first, but in effect that is what I see happening on my system. My read speed, with Read Striping turned on, in those cases is almost exactly the same as the read speed on my SSD.
FYI, I only have 1 SSD, so I do not know if DrivePool would Read Strip both of your SSDs and almost double your read speed from the SSDs. Also, in my case, the bottleneck on my transfers is not the DrivePool read speeds, it is the speed of which I can transfer the data over my home network ethernet, the wifi, or to maybe a destination USB HDD. In most of my cases, transfers on my system are slowed down by lots of things but DrivePool is not one of them.